Latios in Black 2

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Level	Movename
Start	Psywave
5	Heal Block
--	Tailwind
--	Snore
--	Icy Wind
--	Sleep Talk
--	Last Resort
--	Outrage
--	Trick
--	Roost
--	Dragon Pulse
10	Helping Hand
20	Dragonbreath
30	Refresh
35	Luster Purge
40	Zen Headbutt
45	Recover
50	Psycho Shift
55	Dragon Dance
65	Heal Pulse
75	Power Split
80	Detect
85	Memento
15	Safeguard
25	Protect
60	Psychic
70	Telekinesis

Learned by TM:

TM	Move	Type	Contests
TM01	Hone Claws
TM02	Dragon Claw
TM03	Psyshock
TM04	Calm Mind
TM05	Roar
TM06	Toxic
TM10	Hidden Power
TM11	Sunny Day
TM13	Ice Beam
TM15	Hyper Beam
TM16	Light Screen
TM17	Protect
TM18	Rain Dance
TM19	Telekinesis
TM20	Safeguard
TM21	Frustration
TM22	Solar Beam
TM24	Thunderbolt
TM25	Thunder
TM26	Earthquake
TM27	Return
TM29	Psychic
TM30	Shadow Ball
TM32	Double Team
TM33	Reflect
TM37	Sandstorm
TM40	Aerial Ace
TM42	Facade
TM44	Rest
TM45	Attract
TM48	Round
TM53	Energy Ball
TM57	Charge Beam
TM65	Shadow Claw
TM67	Retaliate
TM68	Giga Impact
TM70	Flash
TM73	Thunder Wave
TM77	Psych Up
TM78	Bulldoze
TM85	Dream Eater
TM86	Grass Knot
TM87	Swagger
TM90	Substitute
HM01	Cut
HM02	Fly
HM03	Surf
HM05	Waterfall
HM06	Dive
MT	Draco Meteor
MT	Dragon Pulse
MT	Helping Hand
MT	Icy Wind
MT	Last Resort
MT	Magic Coat
MT	Outrage
MT	Roost
MT	Sleep Talk
MT	Snore
MT	Tailwind
MT	Trick
MT	Wonder Room
MT	Zen Headbutt

Through other methods