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But would the +4 EV's be added regardless of which you're trying to increase?e.g. I battle a Bidoof and get 1 HP EV but have the power anklet attached would I get the 1HP EV plus the 4 Speed EV on top of that?

If you're pokemon is at level 100 and you reduce all it's stats by use of berries and say you EV train to add 252 Ev's to HP, would that stats increase if you were to battle online like it would with non level 100 pokemon?

If you know the IVs you can work out how many EVs you have left to give it.

How does that work?

Well if you had done a Lv100 WiFi battle before training it, you would know the IVs of the Pokemon. With a new Lv100 battle, you'd have a different set of stats. These would be due to the EV training you've done. With the untouched stats (before you started EV training) and the current stats, we would be able to determine how many of each EVs, with an error margin of about 3/7 (depending on some stats).See what I mean? (Sorry if I've worded it slightly confusing)